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Quenched Disorder and Disorder Averaging

Quenched disorder is sampled once and held fixed while the quantum or thermal degrees of freedom evolve. The correct observable is therefore computed at fixed disorder and averaged only afterward. This ordering distinguishes ln⁡ZV‾\overline{\ln Z_V} from ln⁡ZV‾\ln \overline{Z_V}, fixes which correlation functions are normalized before averaging, and exposes when rare samples invalidate a statement based only on a typical realization.

Required background. Coherent-state path integrals supplies the Euclidean many-body functional integral. Thermal density operators and KMS supplies the fixed-Hamiltonian ensemble whose disorder average is taken.

Helpful background. Connected correlators and cumulants supplies the cumulant expansion used below.

Let a static scalar potential V(x)V(\mathbf x) couple to the density,

SV=S0+∫0βdτ∫ddx V(x)n(τ,x).S_V=S_0+\int_0^\beta d\tau\int d^d x\,V(\mathbf x)n(\tau,\mathbf x).

An ensemble is part of the model. A common Gaussian choice has

V(x)‾=0,V(x)V(y)‾=ΔC(x−y),\overline{V(\mathbf x)}=0, \qquad \overline{V(\mathbf x)V(\mathbf y)}=\Delta C(\mathbf x-\mathbf y),

where CC is positive as a covariance kernel. White noise means C(r)=δ(d)(r)C(\mathbf r)=\delta^{(d)}(\mathbf r) only below a declared ultraviolet cutoff; correlated disorder retains a finite correlation length ζ\zeta. The distribution tail, not just Δ\Delta, controls rare regions; Lifshits, Gredeskul, and Pastur 1988, ch. 1 develops this ensemble-to-spectrum distinction.

For each realization, ZV=Tr⁡e−βH[V]Z_V=\operatorname{Tr}e^{-\beta H[V]} and ⟨O⟩V=ZV−1Tr⁡(Oe−βH[V])\langle O\rangle_V=Z_V^{-1}\operatorname{Tr}(Oe^{-\beta H[V]}). Quenched quantities are

Fq=−T ln⁡ZV‾,⟨O⟩V‾,F_{\mathrm q}=-T\,\overline{\ln Z_V}, \qquad \overline{\langle O\rangle_V},

not −Tln⁡ZV‾-T\ln\overline{Z_V} and not a ratio of separately averaged numerator and denominator. Jensen’s inequality gives Fq≥FaF_{\mathrm q}\ge F_{\mathrm a} for the annealed free energy Fa=−Tln⁡ZV‾F_{\mathrm a}=-T\ln\overline{Z_V}. The distinction is physical: annealing lets the disorder equilibrate with the matter.

The chapter’s dependency structure is summarized in the following original diagram. Inspect the first arrow: the ensemble and order of averages precede every replica, sigma-model, localization, or glass conclusion.

On a narrow screen, swipe or use the Left and Right arrow keys to pan across the figure. Home and End move to its edges. A full-size link is also available.

A fixed disorder ensemble feeds normalized observables, replica or supersymmetry representations, diffusive modes, interference corrections, and Anderson scaling, with assumptions labeled at each transition.

From quenched input to localization observables. Solid arrows add a derivation; dashed annotations mark ensemble, symmetry, dimension, or scale assumptions. The diagram is schematic and not a phase diagram.

Text description of this diagram · Figure data (JSON)

Cumulants and disorder-induced interactions

Section titled “Cumulants and disorder-induced interactions”

For a general distribution, introduce connected disorder cumulants KpK_p. Averaging a source JJ gives

ln⁡e∫JV‾=∑p=1∞1p!∫Kp(x1,…,xp)J(x1)⋯J(xp).\ln \overline{e^{\int J V}} =\sum_{p=1}^\infty\frac{1}{p!} \int K_p(x_1,\ldots,x_p)J(x_1)\cdots J(x_p).

For the centered Gaussian ensemble only K2=ΔCK_2=\Delta C survives. Because the Euclidean coupling supplies J(τ,x)=−n(τ,x)J(\tau,\mathbf x)=-n(\tau,\mathbf x), averaging the unnormalized Boltzmann factor produces

e−∫Vn‾=exp⁡ ⁣[Δ2∫ddx ddy C(x−y)∫0βdτ dτ′ n(τ,x)n(τ′,y)].\overline{e^{-\int Vn}} =\exp\!\left[ \frac{\Delta}{2}\int d^d x\,d^d y\,C(\mathbf x-\mathbf y) \int_0^\beta d\tau\,d\tau'\,n(\tau,\mathbf x)n(\tau',\mathbf y) \right].

The two independent imaginary times express static disorder. In an effective action the same term appears with a minus sign because the weight is e−Seffe^{-S_{\mathrm{eff}}}. This sign and the double-time structure are useful checks on replica calculations.

For an extensive sample observable XLX_L, define

RX(L)=XL2‾−(XL‾)2(XL‾)2.R_X(L)=\frac{\overline{X_L^2}-(\overline{X_L})^2}{(\overline{X_L})^2}.

RX→0R_X\to0 is self-averaging in the chosen ensemble and limit. It can fail at a random critical point or for observables dominated by broad tails; averages, medians, typical values Xtyp=exp⁡ln⁡X‾X_{\mathrm{typ}}=\exp\overline{\ln X}, and full distributions then answer different questions. Aharony and Harris 1996 show why critical randomness can prevent strong self-averaging.

Rare-region estimates must retain the tail that creates them. A region of volume ℓd\ell^d may occur with probability p(ℓ)∼e−cℓdp(\ell)\sim e^{-c\ell^d} while its relaxation time grows as τ(ℓ)∼ebℓd\tau(\ell)\sim e^{b\ell^d}; eliminating ℓ\ell produces a power-law distribution of times. Replacing the ensemble by its variance alone can erase this physics.

The canonical disorder and glass claim test matrix records which ensemble, limit, and negative test accompany each later claim.

Quenched versus annealed. Let VV be a centered Gaussian variable with variance Δ\Delta and let a toy realization have ZV=eaVZ_V=e^{aV}. Compute FqF_{\mathrm q} and FaF_{\mathrm a}.

Solution

Since ln⁡ZV=aV\ln Z_V=aV, ln⁡ZV‾=0\overline{\ln Z_V}=0 and Fq=0F_{\mathrm q}=0. The Gaussian moment-generating function gives ZV‾=ea2Δ/2\overline{Z_V}=e^{a^2\Delta/2}, so Fa=−Ta2Δ/2F_{\mathrm a}=-Ta^2\Delta/2. Thus Fq≥FaF_{\mathrm q}\ge F_{\mathrm a}, with strict inequality for a2Δ>0a^2\Delta>0.

Nonvisual description of the disorder structure figure

Section titled “Nonvisual description of the disorder structure figure”

This table states the relationships and qualifications shown in the figure above.

Figure element or arrowRelation encodedCondition or resulting statement
Quenched ensembleThe construction begins with P[V]P[V], its correlation length and symmetries, and the order of thermodynamic and disorder limits.The dashed side condition distinguishes ln⁡Z‾\overline{\ln Z} from ln⁡Z‾\ln\overline Z; self-averaging alone does not justify equality.
Ensemble → normalized observablesDisorder observables are normalized by replicas with n→0n\to0 or by boson–fermion supersymmetry.The representation is fixed before any diffusive or localization approximation.
Normalization side conditionConvergence, analytic continuation, and rare-sample tails constrain the normalization step.Failure preserves only the directly defined disorder average, not a controlled replica or supersymmetric continuation.
Normalized observables → retarded–advanced soft modesWeak static disorder produces diffusons and, when symmetry permits, cooperons with pole (Dq2−iω)−1(Dq^2-i\omega)^{-1}.This arrow assumes the weak-disorder regime.
Soft modes → nonlinear sigma modelThe long-wavelength modes are organized into a symmetry-class field QQ with Q2=1Q^2=1 and gradient, frequency, topological, and interaction terms.The displayed expansion requires qℓ≪1q\ell\ll1 and ∣ω∣τ≪1\lvert\omega\rvert\tau\ll1.
Sigma model → interference branchCooperon structure produces weak localization or antilocalization.The sign and channel count depend on symmetry, dephasing, magnetic field, and spin–orbit scales.
Sigma model → interaction branchDiffusive density and spin modes produce Altshuler–Aronov corrections and Finkel’stein flow.Interaction amplitudes and frequency renormalization must use the same normalization as the diffusive action.
Sigma model → class and topology branchThe target space and allowed topological term follow from the symmetry class.The conclusion remains dimension-, boundary-, and energy-specific.
Interference and interaction branches → conductance scalingTheir controlled corrections feed β(g)=dln⁡g/dln⁡L\beta(g)=\mathrm d\ln g/\mathrm d\ln L.A perturbative logarithm is not itself a critical point.
Interaction plus class/topology branches → localization statementThese branches determine which class-, dimension-, energy-, and boundary-fixed localization statement is admissible.Conductance scaling and localization statements jointly require finite-size fits of relevant and irrelevant drift, distributions, boundary conditions, and dephasing cutoffs.
  • Amnon Aharony and A. Brooks Harris, “Absence of Self-Averaging and Universal Fluctuations in Random Systems near Critical Points,” Physical Review Letters 77 (1996) 3700–3703. DOI
  • Ilya M. Lifshits, Sergei A. Gredeskul, and Leonid A. Pastur, Introduction to the Theory of Disordered Systems, Wiley, 1988. WorldCat