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Quantum Phase Transitions and Competing Scales

A quantum phase transition changes the ground state as a nonthermal parameter is tuned. Its zero-temperature fixed point can organize finite-temperature and finite-size behavior, but only within a window bounded by microscopic scales, irrelevant couplings, and other instabilities. The first task is therefore to name every scale and the order of limits.

Required background. Universality Classes and Scaling Functions supplies RG eigenvalues and scaling functions; Thermodynamic Limits, Phases, and Ensemble Equivalence supplies the limits needed to define a phase transition.

Let gg be a Hamiltonian parameter and r=(ggc)/g0r=(g-g_c)/g_0 a dimensionless distance from criticality. A continuous transition has

ξξ0rν,ξτξz,Δξτ1rνz.\xi\sim \xi_0|r|^{-\nu}, \qquad \xi_\tau\sim \xi^z, \qquad \Delta\sim \xi_\tau^{-1}\sim |r|^{\nu z}.

ν\nu is the correlation-length exponent and zz the dynamical exponent. The nonuniversal ξ0\xi_0 and the velocity or damping coefficient relating time to space must be retained when comparing different observables. If several modes have distinct zz or if a dangerously irrelevant coupling creates another time scale, a single ξτ\xi_\tau is insufficient.

At T=0T=0 the thermodynamic limit is taken before diagnosing spontaneous symmetry breaking. In a finite sample of length LL, the critical gap scales as LzL^{-z} only after aspect ratios, boundary conditions, and the leading irrelevant variables are fixed. A generic observable has

O(r,T,L,{ui})=LxOFO(rL1/ν,TLz,{uiLyi}),O(r,T,L,\{u_i\})= L^{-x_O}\mathcal F_O \left(rL^{1/\nu},\,TL^z,\,\{u_iL^{y_i}\}\right),

where yi<0y_i<0 for irrelevant couplings. This formula is a hypothesis to test, not permission to ignore drift: slowly irrelevant variables can dominate accessible sizes.

The equilibrium path integral has extent β=1/T\beta=1/T, so temperature limits temporal correlations. Comparing TT with the zero-temperature gap defines the crossover scale

T(r)rνz.T^*(r)\sim |r|^{\nu z}.

When TTT\ll T^*, the system reflects one adjacent ground-state regime. When TTT\gg T^* but TT remains below microscopic cutoffs, the quantum-critical fixed point can control scaling. This wedge is a crossover region, not generally a finite-temperature phase.

On an ordered side, a separate thermal transition Tc(r)T_c(r) may occur in dimensions and symmetries that permit it. On a disordered side, activation can set in below Δ\Delta. Disorder, interlayer coupling, superconductivity, or a first-order transition may truncate both crossovers. The boson-Hubbard transition provides a canonical example in which density, particle–hole symmetry, and the path through the phase diagram change zz Fisher et al. 1989, §§ III–V.

An irrelevant coupling uu ordinarily gives corrections proportional to ξyu\xi^{y_u}. It is dangerously irrelevant when setting u=0u=0 makes an observable singular or changes the ordered-state structure. Then an additional length ξ\xi' or thermal line can scale with an exponent not fixed by νz\nu z. Examples include the quartic coupling above an upper critical dimension and monopole fugacity near some fractionalized critical points.

Finite density, magnetic field, momentum relaxation, and probe frequency introduce further ratios:

μT,BTyB/z,ΓmrT,ωT.\frac{\mu}{T},\qquad \frac{B}{T^{y_B/z}}, \qquad \frac{\Gamma_{\mathrm{mr}}}{T},\qquad \frac{\omega}{T}.

A proposed scaling collapse that varies only r/T1/(νz)r/T^{1/(\nu z)} is incomplete if any omitted ratio changes across the data set. Analytic backgrounds can also dominate thermodynamics even when the singular part scales correctly.

Continuous, first-order, and avoided transitions

Section titled “Continuous, first-order, and avoided transitions”

Diverging ξ\xi and universal scale invariance characterize a continuous transition. A level crossing or discontinuous order parameter with finite ξ\xi is first order, although finite size rounds it. An avoided critical point can produce a large but finite scaling window. Establishing criticality therefore requires systematic growth of correlation scales, stable exponent estimates, and consistency between independent observables—not only a broad crossover.

  1. If ν=2/3\nu=2/3 and z=1z=1, how does the crossover temperature scale with rr?
Solution

Trνz=r2/3T^*\sim|r|^{\nu z}=|r|^{2/3}. Doubling r|r| multiplies TT^* by 22/32^{2/3}, up to a nonuniversal scale.

  1. At criticality, how should the lowest gap scale in a finite box when z=2z=2?
Solution

With fixed shape and boundary condition, ΔLLz=L2\Delta_L\sim L^{-z}=L^{-2}. Corrections from irrelevant fields add subleading powers; a nonzero thermodynamic intercept would contradict the assumed continuous fixed point.

  • Fisher, M. P. A., P. B. Weichman, G. Grinstein, and D. S. Fisher. “Boson Localization and the Superfluid–Insulator Transition.” Physical Review B 40 (1989): 546–570. DOI.